Tetrahedral zinc in tetrakis(1-methyl-1H-imidazole-κN3)zinc bis(tetrafluoridoborate)
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چکیده
منابع مشابه
Tetrahedral zinc in tetrakis(1-methyl-1H-imidazole-κN 3)zinc bis(tetrafluoridoborate)
In the title compound, [Zn(C(4)H(6)N(2))(4)](BF(4))(2), the Zn(II) ion is in a slightly distorted tetra-hedral coordination geometry, with Zn-N distances in the range 1.980 (2)-1.991 (2) Å. The tetra-hedral angles are in the range 104.93 (9)-118.81 (9)°.
متن کامل1-Methyl-5-nitro-1H-imidazole
In the title compound, C(4)H(5)N(3)O(2), the nitro group is twisted with respect to the imidazole ring by a dihedral angle of 5.60 (2)°. Weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonding is present in the crystal structure.
متن کامل1-Methyl-4,5-dinitro-1H-imidazole
In the title compound, C(4)H(4)N(4)O(4), the two nitro groups are twisted with respect to the imidazole plane, making dihedral angles of 24.2 (3) and 33.4 (4)°. In the crystal structure, the mol-ecules are linked through non-classical inter-molecular C-H⋯O hydrogen bonds.
متن کاملPoly[(μ3-camphorato-κ3 O:O′:O′′)(2-methyl-1H-imidazole-κN 3)zinc(II)]
In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra-hedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three Zn(II) ions, f...
متن کاملBis[2-(3,4-disulfanylphenyl)acetato]bis(2-methyl-1H-imidazole-κN 3)zinc(II)
In the title mononuclear zinc(II) complex, [Zn(C(8)H(7)O(2)S(2))(2)(C(4)H(6)N(2))(2)], the Zn(II) atom, lying on a twofold axis, is coordinated by two O atoms from two 2-(3,4-disulfanylphen-yl)acetate anions and by two N atoms from 2-methyl-imidazole ligands in a distorted tetra-hdral coordination. The crystal structure is stabilized by inter-molecular C-H⋯O and N-H⋯O hydrogen bonds and π-π int...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811054821